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Beilstein J. Org. Chem. 2012, 8, 1831–1838, doi:10.3762/bjoc.8.210
Graphical Abstract
Figure 1: Examples of naturally occurring iminosugars.
Figure 2: The chemical structures of (+)-batzellasides A–C (1a–c).
Scheme 1: Our previous approach to (+)-batzellaside B and retrosynthetic analysis for the new synthetic strat...
Scheme 2: Reagents and conditions: (a) see [22]; (b) MeONa, MeOH, rt; 98%; (c) (i) p-TsOH, MeOH, rt; (ii) BF3·Et2...
Scheme 3: Reagents and conditions: (a) (i) K2CO3, MeOH, rt; (ii) TBSCl, Et3N, CH2Cl2, rt; (iii) BnBr, NaH, Bu4...